![(11bS)-4-Oxide-8,9,10,11,12,13,14,15-octahydro-4-hydroxy-2,6-bis(2,3,4,5,6-pentafluorophenyl)-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 95%, (99% ee),(11bS)-4-氧化物-8,9,10,11,12,13,14,15-八氢-4-羟基-2,6-双(2,3,4,5,6-五氟苯基)-二萘酚[2,1-d:1',2'-f][1,3,2]二氧磷,95%,(99%ee) , 95%, (99% ee)](https://static.jkchemical.com/Structure/913/9135443.png)
(11bS)-4-氧化物-8,9,10,11,12,13,14,15-八氢-4-羟基-2,6-双(2,3,4,5,6-五氟苯基)-二萘酚[2,1-d:1',2'-f][1,3,2]二氧磷,95%,(99%ee) , 95%, (99% ee)
(11bS)-4-Oxide-8,9,10,11,12,13,14,15-octahydro-4-hydroxy-2,6-bis(2,3,4,5,6-pentafluorophenyl)-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 95%, (99% ee)
分子式: C??H??F??O?P
分子量: 688.44
纯度: 95%, (99% ee)
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基本信息
安全信息
化学和物理性质
产品描述
Technical Notes：
1.Chiral Brønsted acid catalysis for enantioselective Hosomi-Sakurai reaction of imines with allyltrimethylsilane .
2.Chiral Brønsted acid catalysis for stereoselective Mannich-type reactions of in situ generated C-alkynyl imines with ß-keto esters.
3.Chiral Brønsted acid catalysis for Mannich-type reaction of N-Boc-iminium intermediates, generated in situ from N-Boc- aminals.
References:
1. Org. Lett., 2011, 13, 2126.
2.Angew. Chem. Int. Ed. 2013, 52, 1 1509.
3.Tetrahedron, 2016, 72, 3687.
