![(S)-2-[[3,5-Bis(trifluoromethyl)phenyl]thioureido]-N-benzyl-N,3,3-trimethylbutanamide, 95%, (98% ee),(S)-N-苄基-2-(3-(3,5-双(三氟甲基)苯基)硫脲基)-N,3,3-三甲基丁酰胺 , 95%, (98% ee)](https://static.jkchemical.com/Structure/913/9135428.png)
(S)-N-苄基-2-(3-(3,5-双(三氟甲基)苯基)硫脲基)-N,3,3-三甲基丁酰胺 , 95%, (98% ee)
(S)-2-[[3,5-Bis(trifluoromethyl)phenyl]thioureido]-N-benzyl-N,3,3-trimethylbutanamide, 95%, (98% ee)
分子式: C??H??F?N?OS
分子量: 505.50
纯度: 95%, (98% ee)
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Technical Notes:
1.aza-MichaeI Reaction - Catalyst for the formal addition of ammonia to nitroalkenes, affording optically active
ß-amino nitro compounds in high yields and enantioselectivities. The approach is based on a novel thiourea- catalyzed aza-MichaeI reaction, by which benzophenone imine serves as a masked ammonia equiv., which is released by hydrolysis.
2.Diels-Alder Reaction - A variety of organocatalysts were screened for the catalysis of the naphthoquinone monoketal Diels-Alder reaction.
References:
1.Chem.-Eur. J., 2010, 16, 13330-13334
2. Beilstein J. Org. Chem., 2013, 9, 1414-1418.
