Technical Notes：

1.Precursor for cyclophane-derived enantiopure phosphines used for kinetic resolution of hydroperoxides .

2.Used as a bridging unit in the design of organic dyes for sensitized solar cells.

3.Used for syntheses of paracyclophane-based bis-silanols and diols.

4.Used for syntheses of a series of ZnP-pCp-oPPV-C60 conjugates covalently connected through 2,2- paracyclophane -oligophenylenevinylene (pCpoPPV) bridges containing one, two, and three 2,2-

paracyclophanes via Horner-Wadsworth- Emmons olefination reactions and/or Heck type Pd-catalyzedreactions.

5.Used in synthesis of nitrogen-containing microporous conjugated polymers via carbazole-based oxidative coupling polymerization.

6.Used in synthesis of bis-pyridyl2.2paracyclophane.

7.Used in the amination of pseudo-ortho dibromo2.2paracyclophane.