![Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II), min. 98%,二氯[(S)-(-)-2,2′-双(二苯基膦)-1,1′-联萘基][(1S,2S)-(-)-1,2-二苯基乙二胺]钌(II) , min. 98%](https://static.jkchemical.com/Structure/600/600780.png)
二氯[(S)-(-)-2,2′-双(二苯基膦)-1,1′-联萘基][(1S,2S)-(-)-1,2-二苯基乙二胺]钌(II) , min. 98%
Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II), min. 98%
分子式: C??H??Cl?N?P?Ru
分子量: 1006.96
纯度: min. 98%
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基本信息
安全信息
存储条件Store at 2-8℃ |
化学和物理性质
产品描述
Technical Note:
1. The NOYORI catalysts are a ruthenium-based system containing a phosphine and 1 2-diamine ligand. The catalysts are used in the highly- efficient, enantio and diastereoselective hydrogenation of simple ketones, usually under the mild conditions of room temperature and 1-10 atm of hydrogen pressure.
References:
1.J.Org. Chem.. 1996.61.4872.
2. Angew. Chem. Int. Ed.. 2001. 40, 40 (review article).
3. J. Am. Chem. Soc.. 1998, 120, 13529.
4. Angew. Chem. Int. Ed.. 1999, 38, 495.
