![(11aS)-(-)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-phenoxy, min. 98% (S)-ShiP,(11aS)-(-)-10,11,12,13-四氢二茚并[7,1-de:1′,7′-fg][1,3,2] 二氧磷杂八环-5-苯氧基 苯基-[(S)-1,1-螺二氢茚-7,7-二基]亚磷酸酯 , min. 98%](https://static.jkchemical.com/Structure/807/807830.png)
(11aS)-(-)-10,11,12,13-四氢二茚并[7,1-de:1′,7′-fg][1,3,2] 二氧磷杂八环-5-苯氧基 苯基-[(S)-1,1-螺二氢茚-7,7-二基]亚磷酸酯 , min. 98%
(11aS)-(-)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-phenoxy, min. 98% (S)-ShiP
分子式: C??H??O?P
分子量: 374.37
纯度: min. 98%
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Technical Notes:
1. Chiral ligands for rhodium-catalyzed arylation of aldehydes with arylboronic acids.
2.Chiral ligands for rhodium-catalyzed arylation of imines with arylboronic acids
3.Chiral ligands for rhodium-catalyzed arylation of a-ketoesters with arylboronic acids.
4.Chiral ligands for palladium-catalyzed asymmetric umpolung allylation of aldehydes .
5.Chiral ligands for rhodium-catalyzed asymmetric hydrogenation of (Z)-ß-arylenamides.
References:
1.Org. Lett. 2006, 8, 1479.
2.Org. Lett. 2006, 8, 2567 .
3.Angew. Chem. Int. Ed. 2008, 47, 4351.
4.Chem. Sci. 2011, 2, 1135.
5.Tetrahedron 2012, 68, 7685.
