(2R,3R)-(-)-2,3-双(二苯基膦)二环[2.2.1]庚基-5-烯 , min. 95%
(2S,3S)-(+)-2,3-Bis(diphenylphosphino)-bicyclo[2.2.1]hept-5-ene, min. 95% (S,S)-NORPHOS
分子式: C??H??P
分子量: 462.51
纯度: min. 95%
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Technical Notes:
1. L igand used in the enantioselective rhodium catalyzed hydrogenation of a -dehydroaminoesters and enamides .
2.Ligand used in the enantioselective rhodium catalyzed hydroboration of cyclopropenes.
3. L igand used in the asymmetric rhodium catalyzed cleavage of racemic 1 ,3-oxazolidines.
References:
1. Angew. Chem., 1979, 91, 655.
2. J. Am. Chem. Soc. 2003, 125, 7198.
3. Adv. Synth. Catal. 2003, 345, 239.