有机膦在催化剂的制备、多功能配体的设计领域占有重要地位。由于有机膦可以形成稳定的配位键，常被用作金属络合物的配体，参与多种催化反应，如羰基加成反应、氢转移反应等。此外，有机膦化合物自身也可作为催化剂，用于不对称合成反应，迄今为止，科学家已设计制备了上千种含磷的手性催化剂和配体。
    百灵威紧跟前沿研究热点，新上线数百种有机膦催化剂和膦配体系列产品，助力不对称合成领域研究！

• 品种全：主要包括手性膦酸类催化剂和手性膦配体系列产品；
• 产品新：还可提供该领域科研工作者开发的新型有机膦催化剂和配体；
• 质量好：纯度高，质控严格，批次质量稳定。

周剑教授科研成果：手性膦酰胺-胺双功能催化剂

品名	CAS	货号
Diethyl ((1S,2S)-2-((3,5-bis(trifluoromethyl)benzyl)amino)cyclohexyl)phosphoramidate, 97% (1S,2S)-2-((3,5-双(三氟甲基)苄基)氨基)环己基膦酰胺二乙酯	/	9333085
Diisopropyl (S)-(1-phenyl-3-(piperidin-1-yl)propan-2-yl)phosphoramidate, 97% (S)-(1-苯基-3-(哌啶-1-基)丙-2-基)膦酰胺二异丙酯	2417471-76-0	9333431
Diphenyl ((S)-(6-methoxyquinolin-4-yl)((1S,2S,4S,5R)-5-vinylquinuclidin-2-yl)methyl)phosphoramidate, 97% ((S)-(6-甲氧基喹啉-4-基)((1S,2S,4S,5R)-5-乙烯基奎宁-2-基)甲基)膦酰胺二苯酯	1860872-42-9	9333093

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张俊良教授科研成果：SadPhos配体

品名	CAS	货号
[S(R)]-N-[(S)-[[2-(Dicyclohexylphosphino)phenyl]phenylmethyl]-2-methyl-2-propanesulfinamide, 95% [S(R)]-N-[(S)-[[2-(二环己基膦)苯基]苯甲基]-2-叔丁基亚磺酰胺	1595319-99-5	9025972
[S(R)]-N-[(S)-[[2-(Diadamantanphosphino)phenyl]phenylmethyl]-2-methyl-2-propanesulfinamide, 95% [S(R)]-N-[(S)-[[2-(二金刚烷基膦)苯基]苯甲基]-2-叔丁基亚磺酰胺	1929530-55-1	9223891
[S(R)]-N-[(S)-[[2-(Dicyclohexylphosphino)phenyl]phenylmethyl]-N,2-dimethyl-2-propanesulfinamide, 95% [S(R)]-N-[(S)-[[2-(二环己基膦)苯基]苯甲基]-N-甲基-2-叔丁基亚磺酰胺	2241598-32-1	9025974
[S(R)]-N-[(1S)-2-(Diphenylphosphino)-1-[[2-(diphenylphosphino)phenyl]ethyl]-2-methyl-2-propanesulfinamide, 95% [S(R)]-N-[(1S)-2-(二苯基膦)-1-[[2-(二苯基膦)苯基]乙基]-2-叔丁基亚磺酰胺	1824731-39-6	9184522
[S(R)]-N-[(S)-(Phenyl)[[5-(diphenylphosphino)-9,9-dimethyl-9H-xanthen-4-yl](phenyl)methyl]-2-methyl-2-propanesulfinamide, 95% [S(R)]-N-[(S)-(苯基)[[5-(二苯基膦)-9,9-二甲基-9H-氧杂蒽]苯基甲基]-2-叔丁基亚磺酰胺	2162939-87-7	9223393

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手性膦酸类有机催化剂

品名	CAS	货号
(11bS)-8,9,10,11,12,13,14,15-Octahydro-4-hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 98%, ee: 99% (S)-5,5',6,6',7,7',8,8'-八氢联萘酚磷酸酯	1193697-61-8	1552295
(11bR)-8,9,10,11,12,13,14,15-Octahydro-4-hydroxy-2,6-di-1-naphthalenyl-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 98%, ee: 99% (R)-3,3'-双(1-萘基)-5,5',6,6',7,7',8,8'-八氢-1,1'-联萘酚磷酸酯	1242066-20-1	2463943
(11bR)-8,9,10,11,12,13,14,15-Octahydro-4-hydroxy-2,6-di-9-phenanthrenyl-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 98%, ee: ≥99% (R)-2,6-双(9-菲基)-8,9,10,11,12,13,14,15-八氢-1,1'-联萘酚磷酸酯	934201-93-1	2772118
(11bR)-8,9,10,11,12,13,14,15-Octahydro-4-hydroxy-2,6-diphenyl-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 98%, ee: 99% (R)-3,3'-二苯基-5,5',6,6',7,7',8,8'-八氢-1,1'-联萘酚磷酸酯	791616-65-4	2463955
(11bS)-2,6-Bis[4-(1,1-dimethylethyl)phenyl]-4-hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 98%, ee: ≥99% (S)-3,3'-双(4-叔丁基苯基)-1,1'-联萘酚磷酸酯	1217901-32-0	2772068
(11bS)-4-Hydroxy-2,6-bis(2,3,4,5,6-pentafluorophenyl)-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 98%, ee: 99% (S)-3,3'-双(2,3,4,5,6-五氟苯基)-1,1'-联萘酚磷酸酯	1882075-20-8	9108771
(11bS)-4-Hydroxy-2,6-bis(2,4,6-tricyclohexylphenyl)-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 98%, ee: ≥99% (S)-3,3'-双(2,4,6-环己基苯基)-1,1'-联萘酚磷酸酯	1309446-14-7	9135447
(R)-3,3'-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate, 98% (R)-3,3'-双[3,5-双(三氟甲基)苯基]-1,1'-联萘-2,2'-二基磷酸氢酯	791616-62-1	789131
(R)-3,3'-Bis[3,5-dimethylphenyl]-1,1'-binapthyl-2,2'-diyl hydrogenphosphate, 98%, ee: 99% (R)-3,3'-双(3,5-二甲基苯基)-1,1'-联萘酚磷酸酯	861909-53-7	1809240

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手性膦配体

品名	CAS	货号
(R)-[1,1'-Binaphthalene]-2,2'-diylbis[1,1-diphenyl-1,1'-phosphine oxide], 97%, ee: 98% (R)-[1,1'-联萘]-2,2'-二基双[1,1-二苯基氧膦]	94041-16-4	2740685
(R)-1-[(SP)-2-(Di-tertbutylphosphino)ferrocen yl]ethylbis(2-methylphenyl)phosphine, 97% (R)-1-[(SP)-2-(二叔丁基膦)二茂铁基]乙基双(2-甲基苯基)膦	849924-76-1	622891
(S)-(+)-1-[(R)-2-(Diphenylphosphino)ferrocenyl]ethyldicyclohexylphosphine, 97% (S)-(+)-1-[(R)-2-(二苯基膦)二茂铁]乙基二环己基膦	162291-02-3	318726
(S)-1-[(RP)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldi-tert-butylphosphine, 97% (S)-1-[(RP)-2-(二环己基膦基)二茂铁]乙基二叔丁基膦	1246841-00-8	2406633
(S)-1-[(RP)-2-(Di-tert-butylphosphino)ferrocenyl]ethyldiphenylphosphine, 97% (S)-1-[(RP)-2-(二叔丁基膦)二茂铁]乙基二苯基膦	223121-01-5	622890
(11bR)-8,9,10,11,12,13,14,15-Octahydro-N,N-bis[(1R)-1-phenylethyl]-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine, 98%, ee: ≥99% (11bR)-8,9,10,11,12,13,14,15-八氢-N,N-双[(1R)-1-苯乙基]-联萘并[2,1-d:1',2'-f][1,3,2]二氧磷杂-4-胺	1389329-66-1	9188725
(11bR)-N,N-Bis[(S)-1-phenylethyl]-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine, 98% (11bR)​-N,​N-双[(S)​-​1-苯基乙基]​-​联萘并[2,​1-​d:1',​2'-​f]​[1,​3,​2]二氧磷杂-​4-​胺	209482-28-0	9135450
(11bR)-N,N-Diethyl-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine, 98%, ee: 99% (11bR)​-N,​N-​二乙基-联萘并[2,​1-​d:1',​2'-​f]​[1,​3,​2]二氧磷杂-​4-​胺	349103-24-8	9188716
1-(11bR)-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-ylpyrrolidine, 98%, ee: 99% 1-(11bR)-联萘并[2,1-d:1',2'-f][1,3,2]二噁磷杂庚英-4-基吡咯烷	736142-26-0	9222458
4-(11bR)-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-ylmorpholine, 98%, ee: 99% 4-​(11bR)​-联萘并[2,​1-​d:1',​2'-​f]​[1,​3,​2]​二氧磷杂-​4-​基吗啉	636559-56-3	9185721
N,N-Bis[(R)-1-phenylethyl]dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine, 98%, ee: 99% N,N-双[(R)-1-苯基乙基]联苯并[d,f][1,3,2]二氧磷杂-6-胺	500103-26-4	623738

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