共价有机框架（COFs）合成研究进展-百灵威

共价有机框架（COFs）是一类由轻质元素通过共价键连接形成的晶态多孔材料，近年来在能源存储、催化、环境修复等领域展现出巨大潜力。

其合成方法不断革新，最新成果包括：

自牺牲客体策略：厦门大学彭丽/李军团队通过盐客体填充孔道保护骨架，显著提升了COFs的结晶度与比表面积（BET达常规方法的15倍），并成功应用于全氟化合物（PFAS）的高效吸附^[1]。
两性离子COFs绿色水热合成：西湖大学徐宇曦团队以DMAP为催化剂，开发了高结晶两性离子COFs，光催化产氢速率达2052 μmol h⁻¹，量子产率47.1%，为当前最优^[7]。
机械球磨-熔融聚合联用：江南大学陆双龙团队结合机械球磨与熔融聚合，制备了聚酰亚胺COFs，用于钠离子电池负极，比容量达213.7 mA h g⁻¹，循环稳定性优异。

百灵威提供高纯度COFs合成用单体和催化剂

品名	CAS	货号
Terephthalaldehyde, 99%, for synthesis 对苯二甲醛	623-27-8	956210
5,10,15,20-Tetrakis(4-aminophenyl)-21H,23H-porphine, 95% 5,10,15,20-四(4-氨基苯)-21H,23H-卟啉	22112-84-1	364996
2,5-Dihydroxy-1,4-benzoquinone 2,5-二羟基-1,4-苯醌	615-94-1	F470695
Methylsuccinic acid, 99% 甲基丁二酸	498-21-5	471239
p-Phenylenediamine, 99%, reagent grade 对苯二胺	106-50-3	930202 危化品

品名	CAS	货号
4-Dimethylaminopyridine, 99%, for synthesis 4-二甲氨基吡啶	1122-58-3	212279
Acetic acid, 99.5%, AR 乙酸	64-19-7	918109 危化品
Iron(III) chloride hexahydrate, 97%, for synthesis 三氯化铁(III)六水合物	10025-77-1	557110 危化品
Sodium hydroxide, 96%, AR granular 氢氧化钠	1310-73-2	955585 危化品

品名	CAS	货号
PTFE beaker, 50 ml 聚四氟乙烯烧杯	/	972776
Quantitative filter paper, medium fast, φ11cm, 100 pieces/pack 定量滤纸	/	988280
Quantitative filter paper, medium fast, φ9cm, 100 pieces/pack 定量滤纸	/	965345
Laboratory consumables, disposable dispenser for laboratory use (without needle), limited to scientific research use only, 3-piece, pp, luer lock tip, 3 ml, 100 pcs 实验室耗材, 实验室用一次性加液器(无针头), 仅限科研使用	/	2736328
HDPE Wide-mouth bottles (with cap), 30 ml, cap without liner, body: HDPE, cap: PP, excellent chemical resistance HDPE 广口试剂瓶 (含盖)	/	9075346

品名	CAS	货号
FindMolecule ELN, Academic Basic ELN电子记录本系统服务	/	9269008
FindMolecule IMS, Academic Basic 实验室库存管理系统服务	/	9269003
Smart Hazardous Chemical Management Cabinet HCA00, Container size: 900 * 500 * 1980mm, internal size: 650 * 420 * 1550mm, volume 423L RFID酸碱柜HCA-400	/	9410144

品名	CAS	货号
Bio-Vanguard® Disinfectant Spray 清萨灵®消毒剂	/	916670
Bio-Vanguard® Antimicrobial Rinse-free Foaming Hand Sanitizer 清萨灵®泡沫抗菌免水洗手液	/	965255
Antibacterial polycotton laboratory coats, L（170-175cm，60-70kg）涤棉抗菌实验服	/	966163

Peng L., Li J. et al. Synthesis of high quality two dimensional covalent organic frameworks through a self-sacrificing guest strategy. Nature Communications, 20251.
Lan Y. et al. Helical Nanofiber COFs Enhance High-Rate Performance of Lithium Metal Batteries. Angewandte Chemie International Edition, 20254.
Lu S. et al. Mechanochemical Synthesis of Polyimide COFs for Sodium-Ion Batteries. Chemical Communications, 20253.
Van der Voort P. et al. Mild and Scalable Solvothermal Synthesis of Imine-Linked COFs. Angewandte Chemie International Edition, 20242.
Luo F. et al. Top-Down Synthesis of COFs for Uranyl Ion Capture. Nano Letters, 20246.
Xu Y. et al. Green Hydrothermal Synthesis of Zwitterionic COFs for Photocatalysis. Journal of the American Chemical Society, 20237.
Liu W. et al. Twisted Hydrophobic COFs for Antibiotic Degradation. Nature Communications, 2023

共价有机框架（COFs）合成研究进展